So your running larger than stock tires, and a stock alignment most likely performed by some shop monkeys that think within spec is close enough.
Good Luck with that!
Now to be more helpful.
Wider tires will grab ruts more, stock GM alignment specs sucked from the factory IMO. GM basically took a 4x4 s10, lowered it, changed tires, changed to AWD, etc and said yep 4x4 alignment specs will work.
We as owners, lower them further, change rims, tires, parts wear some and wonder why it handles worse.
My suggestion for you would be
Caster 7 deg, both sides EQUAL, not close, not within a spec but EQUAL. Soemtimes they try to adjust 1 side more than another to compensate for crown of the road, but have you seen 2 roads have the exact same crown?
Camber 0 deg to -1/4 deg both sides.
Toe in 1/16"-1/8"
I do my own alignments, I have the same size tires. I just drove an average of 125mph for 120 miles, drive it couple times a week, etc. My truck stays in the lanes, no problem.